Journal of Health and Safety at Work

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Introduction: Noise is one of the most common health hazards at the workplaces that can cause not only somatic problems, but also adversely affect mental health. The aim of this study was to investigate and evaluate occupational noise exposure and noise annoyance in one of the petrochemical companies.

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Material and Method: The study population included 47 people working in Administrative and Manufacturing parts of the petrochemical company. First, dosimetry of production workers and noise frequency analysis of Administrative employees were performed. Then, self-report questionnaire for the assessment of noise annoyance at workplace was completed by the subjects. The questionnaire consisted of three parts: scoring of the noise intensity in the workplace, scoring of the noise annoyance in the workplace and determining the feelings and emotions (e.g. fatigue, sleepiness, and concentration problems) that experienced by subjects during the working day.

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Result: The results of noise dosimetry measurements showed that mean eight hour equivalent continuous A-weighted sound pressure level was 86.13 dBA. According to the frequency analysis of office rooms, mean noise level and Preferred Noise-Criteria (PNC) was 69.4 dBA and 62 dB, respectively. The findings of our analysis revealed that 17.9% of administrative staff and 63.2% of manufacturing workers assigned “very high” score to the noise intensity in the workplace. The annoyance score was obtained “very annoyed” by 10% of employees of office section and 42% of manufacturing workers. For noise-related complaints and sensations defined by subjects, 49% of administrative staff and 60% of manufacturing workers marked the “sometimes” and “more” item of the questionary.

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Conclusion: Based on the obtained results of investigating the noise level (objective exposure) as well as the noise annoyance (subjective exposure) at the studied company, it is necessary to adopt the management –technical noise reduction measures at manufacturing sectors as the personal noise exposure and environmental noise exposure and also noise personal exposure of administrative staff can be decreased.

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Introduction: Heat stress is considered as one of the hazardous occupational agents in hot environments. Working under heat stress condition may lead to individuals’ health problems. Several studies have been shown that stress in the working environments can elevate stress hormones such as cortisol. Since heat stress is one of the serious stresses in hot industries including melting, this study was done to investigate the effect of heat stress on the cortisol concentration of workers in one of the melting industries.
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Material and Method: In this cross-sectional study, 70 workers in two groups of case and control (35 people in case group from foundry unit and 35 people in control group from casting unit without heat stress) were investigated. First, a demographic questionnaire was complete for each subject. Then in order to evaluate the changes in cortisol level, blood samples were taken from the participants during their working hours (9:30 to 10 AM) and the obtained levels were compared with the normal level of cortisol, provided at 7 to 10 AM. In order to assess environmental condition, WBGT (Wet Bulb Globe Temperature) index was measured at three highest including feet, waist and head. Moreover, noise and lighting were measured at the workers work station. Data were analyzed using SPSS software version 16.
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Result: Regarding WBGT, it was shown that mean WBGT index were 33 C and 16.7 C in case and control groups, respectively. Additionally, cortisol concentration in case group was significantly higher than control group (P<0.001).
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Conclusion: Results of the present study indicate that physical stresses of working environment can lead to changes in physiology of human body. Thus, variations in hormone level in its consequences in hot environment should be considered in occupational hygine.

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Introduction: Polycyclic aromatic hydrocarbons (PAHs) are one of the most significant current environmental issues. Phenanthrene and naphthalene adsorption at activated carbon beds prevent the release of these compounds into the environment. The objective of this research was to compare the amounts of phenanthrene and naphthalene adsorption at activated carbon beds in the n-hexane solution.

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Material and Method: This discontinuous experimental study was conducted in the laboratory scale batch and in the n-hexane solution containing phenanthrene and naphthalene.PH values were adjusted by adding hydrochloric acidand 1 N NaOH. The initial and residual phenanthrene and naphthalene concentrations were spectrophotometrically measured at 270 and 266 nm, respectively.

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Results: Findings showed that the maximum adsorption of naphthalene was obtained at pH=5 and contact time of 8 hours (7.4 mg/gr). The maximum adsorption was reached at pH=7 and contact time of 11 hours for phenanthrene (8.34 mg/gr).Improvement in the adsorption capacity was happenedby the increases in contact time and initial phenanthrene and naphthalene concentrations. The adsorption kinetics of these two compounds followed pseudo-second-order and Freundlich isotherm model.

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Conclusion: Freundlich isotherm model showed a strong association with PAHs adsorption process. A weak correlationwas observed between Langmuir theory and the results of the adsorption at activated carbon beds in the organic n-hexane solution.

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Introduction: Nowadays, exposure to extremely low frequency (ELF) magnetic field has been interested in many studies due to possible effects on human physical-mental health. Therefore, this study aimed to assess arc welders’ exposure to extremely low frequency magnetic field and to determine its relationship with the secretion of paratormone (PTH) hormone and mood states.

Material and Method: The present study has been conducted among 35 healthy production workers (as exposed group) and 35 healthy administrative personnel (as unexposed group). After checking the work activities of participants according to the guide recommended by the National Institute for Occupational Safety and Health (NIOSH), ELF magnetic fields were measured using an ELF measurement device in the regions including trunk, head, and neck. The plasma levels of PTH hormone of both groups were evaluated by the Electrochemiluminescence method. Stress-Arousal Checklist (SACL) was used to assess the mode states of subjects in both groups. The collected data were analyzed by SPSS software version 16.

Result: There was a significant difference between the exposed and unexposed groups with respect to the exposure level to ELF magnetic fields (P-value<0.0001). Mean PTH hormone level in exposed group (34.54 pg/ml) was lower than unexposed ones (37 pg/ml), however these mean values weren’t significantly different (P-value=0.67). Score of “stress” subscale related to the “pleasure” and score of “arousal” subscale  related to the “activities and alertness” in the unexposed group were significantly higher than those in exposed group (p<0.0001). Regarding the relationship between exposure level to ELF electromagnetic field and scores of  stress, arousal, and PTH hormone level in the two groups, it should be stated that only a significant and positive association was found between the average exposure to ELF magnetic fields and PTH levels in the exposed group (P-value<0.009, r=0.44).

Conclusion: The results of this study showed that continuous welding can be considered as an exposure source to extremely low frequency electromagnetic fields. More accurate and comprehensive laboratory and field studies are needed to prove the hypothesis of the potential impact of extremely low frequency magnetic fields on people’s psychological states and mood through changes of parathyroid hormone level.

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Introduction: Nowadays, Shielded Metal Arc Welding (SMAW) is the most widely used arc welding. During the welding operation, typically, various harmful agents such as fumes, gases, heat, sound and ultraviolet radiation are produced of which fume is the most important component from the viewpoint of occupational health. The present study aims to compare the number and the mass concentration emitted in SMAW to determine the most appropriate index of exposure to fumes in the welding processes.

Material and Method: In this study, the portable laser aerosol spectrometer and dust monitor of GRIMM, model 1.106, was used to measure the number and mass concentration of fumes emitted from SMAW on 304 stainless steel with a thickness of 0.4 mm. Air sampling was performed at a distance of 41 cm representing the welder’s breathing zone. The measurements of number concentration (NC) and mass concentration (MC) were taken under the condition of 25 volt voltage and direct current of the electrode polarity.

Result: The total NC and MC of welding fumes in welder’s breathing zone was 1140451 particles per liter and 1631.11 micrograms per cubic meter, respectively. The highest number concentration was found to correspond to the particles with 0.35 to 0.5 micrometer-sized distribution (NC1; 938976 particles per liter) and the lowest was related to the particles with 5 to 6.5 micrometer-sized distribution (NC7; 288 particles per liter) and the particles larger than 6.5 micrometer (NC8; 463 particles per liter). Moreover, the highest mass concentration was related to the particles with 0.35 to 0.5 micrometer-sized distribution (MC1; 450 micrograms per cubic meter) and the particles larger than 6.5 micrometer (MC8; 355 micrograms per cubic meter).

Conclusion: The findings indicated that there is no agreement between number and mass concentration as two particles assessment index, and as the particles’ size become smaller, the mismatch of them is becoming more apparent. Since the smaller particles penetrate into the lower respiratory tract and have higher potential for adverse health effects, it is necessary to measure and assess particles in various size distributions and especially the smaller fraction of particles. Therefore, it is thought that considering the mass concentration alone and not paying attention to number concentration in the assessment of exposure to particles in the industrial workplaces and specifically in welding stations will not be reflected valid assessment of adverse health effects of welding fumes as a systemic poison on body organs.

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Introduction: Exposure to crystalline silica dust can seriously threaten health of workers engaged in processes such as casting, stone crushing, grinding, construction activities, insulator manufacturing, and glassblowing and sandblasting. The aim of this study was to assess occupational exposure to crystalline silica and to determine the risk of mortality from silicosis and lung cancer in an insulator manufacturer.

Material and Method: Air personal sampling was performed using 10 mm nylon cyclone and mixed cellulose ester (MCE) membrane filters (5 mm diameter, 0.8 μm pore size) for 60 male workers. Samples were prepared and analyzed according to the National Institute for Occupational Safety and Health (NIOSH) 7601 standard method. The risk assessment of mortality due to silicosis resulting from crystalline silica exposure was done by using model of Mannetje et al. for the period of 10 years. The mortality rate of lung cancer was determined using a linear regression model derived from the study Rice et al.  

Result: The highest and lowest exposure levels to silica were belonged to the packing unit (0.54±0.28 mg/m3) and the furnace (0.02±0.01 mg/m3), respectively. Crystalline silica concentrations for all samples were higher than Threshold Limit Values (0.025 mg/m3) recommended by the American Conference of Governmental Industrial Hygienists (ACGIH). According to Mannetje et al. model, the cumulative exposure of 25% workers was in the range 0 to 0.99 that it represents 1 death per 1,000 people. The risk of mortality due to lung cancer was obtained in the range of 7-94 persons per 1000 workers exposed to silica.

Conclusion: In general, the geometric and arithmetic mean of crystalline silica exposure was higher than threshold limit value for most of the subjects. For all workers of the insulator manufacturer, the risk of silicosis related mortality was higher than 1/1,000 (unacceptable level of risk). Predicting the lung cancer mortality from silica exposure indicated a high level of mortality risk among understudied workers.

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Introduction: Electrospun nanofibers are suitable option to synthesize filtering mats for nanoparticles. This study was aimed to fabricate polyurethane nanofiber mats through electrospinning process and to investigate the effect of different parameters such as packing density, face velocity and particle type on the filtration efficiency and quality factor of electrospun polyurethane nanofiber mats.
 

Material and Method: The nanofiber mats were produced by electrospinning  process. Polyurethane granules were dissolved (15w/w%) in a solvent system consisting of dimethylformamide and tetrahydrofuran (3:2). Then, the filtration performance testing system was made at the Fluid Mechanics Department of Hanyang University of South Korea and the filtration efficiency and pressure drop of prepared nanofiber mats were studied.
 

Result: Findings showed that by increasing the duration of electrospinning, the basis weight, thickness, packing density, initial pressure drop and filtration efficiency of the mats increased, and the quality factor of the mats decreased due to the increase of the pressure drop. The increase in electrospinning duration from 15 to 45 minutes was led to the increase in pressure drop from 7 to 32 Pa and the average filtration efficiency was increased about 9-10% for KCl and DEHS test particles. The filtration efficiency and quality factor of the prepared polyurethane nanofiber mats were declined with the increase of filtration face velocity from 2 to 5 and 10 cm/s. The reduction in filtration efficiency was more obvious for particles smaller than 425 nm.
 

Conclusion: The results demonstrated that prepared polyurethan naofiber mats provide acceptable filtration performance. What is more, such nanofiber mats can have other potential benefits such as light basis weight, low thickness and simple production.

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Introduction: Heat stress is one of the hazardous agents in the steel industries which can threaten the health and safety of workers and lead to serious occupational diseases. The aim of the study was to assess the heat stress in the steel industries and compare PHS (Physiological Strain Index), WBGT (Wet-Bulb Globe Temperature), DI (Discomfort Index) and HSI (Heat Stress Index) indices for the estimation of heat stress and to determine the optimum index for steel industries.
 

Material and Method: This descriptive-analytic study was conducted among 220 workers engaged in two steel industries in Iran. Environmental and physiological parameters were measured according to ISO 7726 and ISO 9886 in three times of measurement, and finally the time-weight average of the heat stress indices were calculated. All data were analyzed using SPSS ver.  20.
 

Result: The time-weight average of WBGT (28.28 oC), DI (29.11 oC), HIS (65.7 %) indices were higher than the recommended limits. Physiological parameters (oral, tympanic and skin temperatures, systolic and diastolic pressures and heart rate) had the greatest value in the second time of measurement (afternoon). WBGT index comparing to the PHS, DI and HSI indices had highest correlation with oral, tympanic and skin temperatures and heartbeat (r=0.314 , 0.408 , 0.459 , 0.302, respectively; P < 0.05), while systolic and diastolic blood pressures showed no significant correlation with WBGT (P > 0.05). The WBGT index had the highest correlation with studied indices which was 0.945, 0.681 and 0.600 for DI, PHS and HSI, respectively.
 

Conclusion: This study assessed the optimal index with regard to the physiological parameters, and it was concluded that the WBGT index has the highest correlation with the most of physiological parameters, and therefore, WBGT index can be the most optimum index to heat stress assessment   in the studied steal industries.

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Introduction: Indoor air environments contain a wide variety of microorganisms such as bacteria, fungi, and viruses in which some of them can affect the human health. Filtration is considered as one of the most common methods to remove microorganisms in these environments. The purpose of current study was to investigation the neat and photocatalytic HEPA filters performance at different face velocities and various intensity of UVC light source on the reduction of airborne microorganisms.

Material and Method: After installation of the neat and photocatalytic HEPA filters in a closed–loop chamber, suspension of Staphylococcus epidermidis and Bacillus subtilis bacteria with a concentration of 107 CFU / ml were sprayed into the closed–loop chamber by nebulizer. Sampling of penetrated microorganisms from filters were performed using the NIOSH 0800 method under ambient temperature 22±3oC, relative humidity 35±5%, and different air velocity (0.1 m/s and 0.3 m/s) and UVC different radiation intensity (1 mW/cm2, 1.8 mW/cm2 and no radiation (dark)) at 30 minutes time period. penetrated microorganisms density from filters was determined in term of CFU/m3.

Result: There were no significant differences in the penetration rates of microorganisms at the dark mode between the two neat and photocatalytic HEPA filters (p>0.05). The penetration rate of bacteria was significantly decreased in the neat and photocatalytic HEPA filters at UVC radiation mode with various intensities than dark mode (p<0.05). In addition, comparison of the filters in the illuminance modes of 1 mW/cm2 and 1.8 mW/cm2 were statistically significant (P <0.05). Also, UVC radiation with the 1.8mW/cm2 illuminance compared to the 1 mW/cm2 illuminance resulted in a greater reduction in the bacterial penetration from both types of filters, which is statistically significant(p<0.05). The bacteria penetration rate dramatically increased by increasing the face velocity from 0.1 m/s to 0.3 m/s under UVC radiation at an illuminance of 1mW/cm2, 1.8mW/cm2 and as well as in no radiation mode in both types of HEPA filters (P <0.05).

Conclusion: Photocatalytic HEPA filters and increasing UVC illuminance, especially at lower surface velocities, have a significant positive effect on reducing airborne microorganisms and increasing the efficiency of HEPA filters

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Introduction: Nowadays, millions of people are exposed to the dusts in their workplaces. Occupational exposure to dusts is considered as one of the most common and serious occupational hazards to workers’ health. The purpose of this literature review was to review the literature related to the occupational exposure to dusts in Iran published over the past 14 years.  
Material and Methods: In this review, published articles were obtained from Web of Science, PubMed, Google Scholar, Scopus, ScienceDirect, Islamic World Sciences Citation (ISC), Magiran, SID، Iran Medex, and Civilica search engine. The main keywords for search were Occupational Exposure, Lung, Dust, Total Dust, and Respirable Dust. The relevant articles published in Iran over the past 14 years were searched and extracted after checking their relevancy. All articles were classified based on the titles, years of publication, places of publication, type of industries, geographic distributions, sampling and analysis methods, fields of study, and the amounts of exposure.
Results: Findings showed that in spite of increases in the rate of published literature in recent years and by considering geographical variation and the large number of dust generating firms and industries, a relatively small number of studies was conducted and published in this field. Majority of the studies in this field considered the levels of dust exposure and respiratory effects of dust exposures.  In most studies the levels of occupational exposure to dusts (and crystalline silica dusts) were higher than the recommended limit values.
Conclusion: Although an increasing number of studies can be seen in recent years on occupational exposure to dusts and their effect, by considering the presence of large and small size industries with dust generating pollution  in Iran, the large number of exposed people, adverse-health  effects,  and  the need for control measures, few studies have been published in this field and further works need to be done in this area.

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Introduction: Despite nanofibers have attracted great interests for filtering particulate matters from the air stream, fewer studies have been done on the feasibility of their use in the removal of gas pollutants, while the both pollutants are present in the most workplaces. Toluene is a toxic and mutagenic substance, and chronic exposure to its low levels can lead to a wide range of adverse health effects on people who exposed. The purpose of this study was to produce polymer /single-walled carbon nanotube hybrid nanofibers by electrospinning technique and doing plasma surface treatment and evaluating their removal efficiency of toluene from air stream.  
Material and Methods: The nanofiber layers were fabricated by electrospinning solution containing polyacrylonitrile polymer (PAN) and single-walled carbon nanotube (SWNT) with a 99: 1 ratio under following conditions: applied voltage 20 kV, distance between needle and collector: 10 cm, injection rate: 1 ml / h; needle diameter: 18 gauge and drum speed ranging from 1000 to 500 rpm. The surface of the manufactured nanofibers was treated by cold-plasma with a radio frequency power supply (13.56 MHz with a power of 20 watts), argon gas and operating pressure of 0.2 torr. Test conditions was prepared according to standard ISO 10121-1: 2014, which provides a method for testing the performance of gas-phase air filter for a variety of flat sheet media. In order to measure the concentration of toluene, the First check – handheld multi gas VOC detector equipped with a PID detector was used. The morphology characteristics of the fibers was performed using the analysis of scanning electron microscope images. Infrared spectroscopy-Fourier transform was used to identify organic compounds and functional groups in nanofibers.
Results: The results of the analysis of the images showed that the mean diameter of the fiber was 169.16 ± 7.19 nm and the mean coefficient of variation was 0.23. The uniform and bead nanofibers were obtained. The thickness, porosity and air permeability coefficient of test media was 0.15 mm, 43% and 5.75 Darcy, respectively. The mean removal efficiency of PAN / SWNT nanofiber treated with plasma was 98% and the mean pressure drop was 100 Pascal. The FTIR spectrum of the test filter media showed that the peaks appearing at certain wavelengths related to the vibration of C-H aliphatic groups of C-C and C=O bands related to PAN polymer and carbon nanotubes.
Conclusion: Removal of toluene was achieved through the fabrication of PAN/SWNT hybrid nanofibers treated with plasma. Uniform nanofibers were obtained and showed the proper removal efficiency and low pressure drop.

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Introduction: Studies show that in many cases, environmental hazardous agents such as heat, noise, as well as chemical pollutants cause adverse health effects through the mechanism of oxidative stress. This study has examined the effect of exposure to noise and whole-body vibration (WBV) on some parameters of oxidative stress (enzyme superoxide dismutase (SOD), total antioxidant capacity (TAC), and malondialdehyde (MDA)) of workers in a foundry industry.
Material and Methods: The workers were selected based on the calculations related to the sample size and taking into account the inclusion criteria as well as completing the informed consent form. The level of exposure to noise and WBV was measured according to ISO 9612 and ISO 2631, respectively. For each worker, the time-weighted average was calculated. The level of exposure of workers to the studied stressors was divided into three categories: low, medium, and high. The blood samples were taken from all participants between 7-9 am. Then, via ELISA method according to the protocol of the kit manufacturer, the samples were prepared and analyzed. Univariate analysis of variance was performed to determine the “effect size” of each physical stressors on the studied parameters.
Results: The mean levels of MDA, SOD, and TAC among participants were 22.48 (11.19) nmol / ml, 61.28 (10.97) U / ml, and 1.64 (0.90) mM, respectively. Among the exposure variables, noise had the largest effect on MDA level (B = 0.090), which was not statistically significant (P = 0.865). WBV had the largest effect on SOD level (B = -1.469) which was statistically significant (P = 0.016). None of the studied variables had a significant effect on the TAC level; however, among the exposure variables, the greatest effect was related to WBV (B = -0.077; P = 0.133).
Conclusion: The effect of noise on oxidative stress parameters was not statistically significant. The effect of whole-body vibration on oxidative stress parameters except SOD was not statistically significant. Noise and WBV had increasing effect on MDA and decreasing one on SOD and TAC levels.

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Introduction: Due to uncertainties regarding the risks of engineered nanomaterials for human health and the environment, different organizations and researchers have developed various management frameworks and assessment tools to mitigate hazards during the procedures and applications of engineered nanomaterials. However, most of these techniques do not meet all the individual requirements. This study provides a review and introduction to the techniques developed for the management of safety, health, and environmental risks associated with engineered nanomaterials.
Material and Methods: In order to find pertinent documents on the safe handling of engineered nanomaterials, a search was conducted using the following keywords: “Engineered nanomaterials”, “Framework”, “Tool”, “Risk management”, “Occupational exposure”, “Environment”, “Risk assessment”, and “Nanotechnology”. The search was conducted on various databases, including Scopus, Web of Science, NIOSH, ECHA, and ISO. Among the search results, tools and frameworks that specifically focus on the safety, health, and environmental risk management or assessment of engineered nanomaterials were selected.
Results: Among the search results, 17 frameworks and 11 developments in the field of managing occupational, environmental, and toxicological risks associated with engineered nanomaterials were discussed. Various frameworks and tools for identifying, evaluating, and managing the potential risks of engineered nanomaterials vary in terms of their scope, goals, risk assessment approaches, and output, offering diverse applications.
Conclusion: Various tools and frameworks, each with unique properties, applications, and limitations, can assist organizations in achieving their goals related to safety, health, and environmental issues in the field of nanotechnology. Currently, there is no consensus on the optimal approach for assessing the risks of nanomaterials, underscoring the necessity for additional research, development, and collaboration in this field.